Low-Frequency Mechanical Spectroscopy of Lanthanum Cobaltite Based Mixed Conducting Oxides
نویسندگان
چکیده
منابع مشابه
Proton-conducting Oxides
■ Abstract The structural and chemical parameters determining the formation and mobility of protonic defects in oxides are discussed, and the paramount role of high-molar volume, coordination numbers, and symmetry are emphasized. Symmetry also relates to the structural and chemical matching of the acceptor dopant. Y-doped BaZrO 3-based oxides are demonstrated to combine high stability with high...
متن کاملHighly stable, mesoporous mixed lanthanum–cerium oxides with tailored structure and reducibility
Pure and mixed lanthanum and cerium oxides were synthesized via a reverse microemulsion-templated route. This approach yields highly homogeneous and phase-stable mixed oxides with high surface areas across the entire range of La:Ce ratios from pure lanthana to pure ceria. Surprisingly, all mixed oxides show the fluorite crystal structure of ceria, even for 10 lanthanum contents as high as 90%. ...
متن کاملTowards an Improved Understanding of Electrochemical Oxygen Exchange Reactions on Mixed Conducting Oxides
In solid oxide fuel cells or electrolysis cells with ionic and electronic conducting electrodes, the electrochemical reactions take place at the gas/solid interface of the mixed conducting electrode. This is in contrast to the situation met in aqueous electrolytes, where the reactions occur at the electrode/electrolyte interface. Thus, modified concepts are required to describe the reaction rat...
متن کاملOxygen surface exchange kinetics of SrTi(1-x)Fe(x)O(3-δ) mixed conducting oxides.
The oxygen surface exchange kinetics of mixed conducting perovskite oxides SrTi(1-x)Fe(x)O(3-δ) (x = 0, 0.01, 0.05, 0.35, 0.5) has been investigated as a function of temperature and oxygen partial pressure using the pulse-response (18)O-(16)O isotope exchange (PIE) technique. Arrhenius activation energies range from 140 kJ mol(-1) for x = 0 to 86 kJ mol(-1) for x = 0.5. Extrapolating the temper...
متن کاملMechanical properties of graphene oxides.
The mechanical properties, including the Young's modulus and intrinsic strength, of graphene oxides are investigated by first-principles computations. Structural models of both ordered and amorphous graphene oxides are considered and compared. For the ordered graphene oxides, the Young's modulus is found to vary from 380 to 470 GPa as the coverage of oxygen groups changes, respectively. The cor...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Archives of Metallurgy and Materials
سال: 2016
ISSN: 2300-1909
DOI: 10.1515/amm-2016-0272